(49-6) 41 * << * >> * Russian * English * Content * All Issues
Optical and Electrophysical Properties of Thin Anisotropic Films Based on Carbyne Stabilized by Gold Particles
V. Samyshkin 1, A. Osipov 1, D. Bukharov 1, A. Lelekova 1, A. Abramov 1, A. Kuznetsov 1, A. Kucherik 1
1 Physics and Applied Mathematics dept., Vladimir State University,
Vladimir 600000, Gor’kogo str., 87, Russia
PDF, 1424 kB
DOI: 10.18287/COJ1841
Pages: 1243-1246.
Full text of article: English language.
Abstract:
This study considers the optoelectrical properties of thin films composed of linear carbon stabilized by gold nanoparticles. We explore the unique anisotropic behaviors exhibited by these films and their dependence on the degree of structural ordering. The fabrication process includes the use of colloidal systems, with a focus on the laser-induced fragmentation of gold nanoparticles within a carbon matrix. Our findings reveal that applying a potential difference significantly alters the absorption characteristics of the films, particularly enhancing absorption at frequencies associated with short linear chains, while also inducing a transparency effect in the visible range. The introduction of electrons into the carbon matrix is identified as a key factor influencing these optical properties, drawing parallels to existing literature on resonance pumping phenomena. Additionally, the results indicate a considerable modification of the Schottky barrier at the semiconductor-metal interface due to structural orientation. This research provides insight into the potential applications of these materials in optoelectronic devices and highlights the importance of structural characteristics in tailoring their properties.
Keywords:
optoelectrical properties, anisotropic properties, linear chains, semiconductor-metal interface.
Citation:
Samyshkin V, Osipov A, Bukharov D, Lelekova A, Abramov A, Kuznetsov A, Kucherik A. Optical and electrophysical properties of thin anisotropic films based on carbyne stabilized by gold particles. Computer Optics 2026; 49(6): 1243-1246. DOI: 10.18287/COJ1841.
Acknowledgements:
This work was supported by the framework of RSF grant 23-12-20004 (https://rscf.ru/project/23-12-20004/) and the state assignment in the field of scientific activity of the Ministry of Science and Higher Education of the Russian Federation (theme FZUN-2024-0019, state assignment of the VlSU).
References:
- Sajanlal PR, Sreeprasad TS, Samal AK, Pradeep T. Anisotropic nanomaterials: structure, growth, assembly, and functions. Nano Rev 2011; 2: 5883. DOI: 10.3402/nano.v2i0.5883.
- Sharme RK, Quijada M, Terrones M, Rana MM. Thin Conducting Films: Preparation Methods, Optical and Electrical Properties, and Emerging Trends, Challenges, and Opportunities. Materials 2024; 17: 4559.
- Schneider G, Decher G, Nerambourg N, Praho R, Werts MHV, Blanchard-Desce M. Distance-dependent fluorescence quenching on gold nanoparticles ensheathed with layer-by-layer assembled polyelectrolytes. Nano Lett 2006; 6(3): 530-536.
- Pichon BP, Louet P, Felix O, Drillon M, Begin-Colin S, Decher G. Magnetotunable Hybrid Films of Stratified Iron Oxide Nanoparticles Assembled by the Layer-by-Layer Technique. Chem Mater 2011; 23: 3668-3675.
- Thorkelsson K, Bai P, Xu T. Self-assembly and applications of anisotropic nanomaterials: A review. Nano Today 2015; 10: 48-66.
- Pan B, et al. Carbyne with finite length: The one-dimensional sp carbon. Science Advances 2015; 1(9): e1500857.
- Kutrovskaya S, et al. Excitonic fine structure in emission of linear carbon chains. Nano Letters 2020; 20(9): 6502-6509.
- Rozhkova N, Rozhkov S, Goryunov A. Natural graphene-based shungite nanocarbon. Carbon nanomaterials sourcebook: graphene, fullerenes,nanotubes and nanodiamonds. Ch 7. CRC Press; 2016.
- Kucherik A, Osipov A, Samyshkin V, Hartmann RR, Povolotskiy A, Portnoi ME. Polarization-sensitive photoluminescence from aligned carbon chains terminated by gold clusters. Phys Rev Lett 2024; 132: 056902.
- Garnov SV, Abramov DV, Bukharov DN, Khudaiberganov TA, Khor’kov KS, Osipov AV, Zhirnova SV, Kucherik AO, Arakelyan SM. Electrophysics of carbon 1D structures obtained in a laser experiment: models and demonstration. Phys–Usp 2024; 67: 109-128.
- G. Li, A. Luican, J. M. B. Lopes dos Santos, A. H. Castro Neto, A. Reina, J. Kong, E. Y. Andrei Observation of Van Hove singularities in twisted graphene layers. Nature Physics 2010; 6: 109-113.
- Al-Backri A, Zólyomi V, Lambert CJ. Electronic properties of linear carbon chains: Resolving the controversy. J Chem Phys 2014; 140(10): 104306.
- Antipov AA, Arakelyan SM, Kutrovskaya SV, Kucherik AO. Electrical properties of metal cluster structures formed on the surface of dielectrics. Tech Phys Lett 2014; 40: 529-532.
- Cataldo F. Synthesis of polyynes in a submerged electric arc in organic solvents. Carbon 2004; 42: 129-142.
- Amendola V, Pilot R, Frasconi M, Maragò OM, Iatì MA. Surface plasmon resonance in gold nanoparticles: a review. J Phys Condens Matter 2017; 29(20): 203002.
- Arutyunyan NR, Kononenko VV, Gololobov VM, Obraztsova ED. Resonant Effects in SERS Spectra of Linear Carbon Chains. Physica Status Solidi (B) 2017; 255(1):1700254.
© 2009, IPSI RAS
151, Molodogvardeiskaya str., Samara, 443001, Russia; E-mail: journal@computeroptics.ru ; Tel: +7 (846) 242-41-24 (Executive secretary), +7 (846) 332-56-22 (Issuing editor), Fax: +7 (846) 332-56-20